全文获取类型
收费全文 | 2057篇 |
免费 | 429篇 |
国内免费 | 522篇 |
专业分类
化学 | 2044篇 |
晶体学 | 25篇 |
力学 | 10篇 |
综合类 | 11篇 |
数学 | 32篇 |
物理学 | 886篇 |
出版年
2024年 | 3篇 |
2023年 | 14篇 |
2022年 | 50篇 |
2021年 | 88篇 |
2020年 | 80篇 |
2019年 | 81篇 |
2018年 | 59篇 |
2017年 | 75篇 |
2016年 | 76篇 |
2015年 | 139篇 |
2014年 | 129篇 |
2013年 | 184篇 |
2012年 | 163篇 |
2011年 | 180篇 |
2010年 | 168篇 |
2009年 | 181篇 |
2008年 | 155篇 |
2007年 | 203篇 |
2006年 | 133篇 |
2005年 | 144篇 |
2004年 | 146篇 |
2003年 | 125篇 |
2002年 | 82篇 |
2001年 | 45篇 |
2000年 | 47篇 |
1999年 | 37篇 |
1998年 | 35篇 |
1997年 | 16篇 |
1996年 | 31篇 |
1995年 | 19篇 |
1994年 | 19篇 |
1993年 | 14篇 |
1992年 | 16篇 |
1991年 | 8篇 |
1990年 | 9篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 3篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1979年 | 5篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有3008条查询结果,搜索用时 281 毫秒
11.
The soliton molecules of the(1+1)-dimensional extended modified Korteweg–de Vries(mKdV)system are obtained by a new resonance condition, which is called velocity resonance. One soliton molecule and interaction between a soliton molecule and one-soliton are displayed by selecting suitable parameters. The soliton molecules including the bright and bright soliton, the dark and bright soliton, and the dark and dark soliton are exhibited in figures 1–3, respectively.Meanwhile, the nonlocal symmetry of the extended mKdV equation is derived by the truncated Painlevé method. The consistent Riccati expansion(CRE) method is applied to the extended mKdV equation. It demonstrates that the extended mKdV equation is a CRE solvable system. A nonauto-B?cklund theorem and interaction between one-soliton and cnoidal waves are generated by the CRE method. 相似文献
12.
《Physics letters. A》2020,384(32):126796
We evaluated the total electron chirality in alanine, serine, and valine, which are molecules that have chiral structures. Previously, computations of the total electron chirality of molecules composed of only light elements are impossible within usual computational conditions of relativistic four-component wave functions. In this work, it is shown that the total electron chirality can be calculated if some diffuse functions are added to Gaussian basis sets. This is demonstrated for the H2O2 molecule. By adding diffuse Gaussian functions to basis sets, the total electron chirality of L-alanine, L-serine, and L-valine are evaluated. It is also shown that the total electron chirality is derived by the cancellation between large contributions from each orbital, and the total electron chirality in excited and ionized states is expected to be much larger than that of the ground state. 相似文献
13.
Cheng-Cheng Tsai Zhi-Yao Tsai Ming-Yu Tseng Wei-Ping Hu 《International journal of quantum chemistry》2020,120(14):e26238
We have developed a new database of structures and bond energies of 59 noble-gas-containing molecules. The structures were calculated by CCSD(T)/aug-cc-pVTZ methods and the bond energies were obtained using the CCSD(T)/complete basis set method. Many wavefunction-based and density functional theory methods have been benchmarked against the 59 accurate bond energies. Our results show that the MPW1B95, B2GP-PLYP, and DSD-BLYP functionals with the aug-cc-pVTZ basis set excel in predicting the bond energies of noble-gas molecules with mean unsigned errors (MUEs) of 2.0 to 2.1 kcal/mol. When combinations of Dunning's basis sets are used, the MPW1B95, B2GP-PLYP, DSD-BLYP, and BMK functionals give significantly lower MUEs of 1.6 to 1.9 kcal/mol. Doubly hybrid methods using B2GP-PLYP and DSD-BLYP functionals and MP2 calculation also provide satisfactory accuracy with MUEs of 1.4 to 1.5 kcal/mol. If the Ng bond energies and the total atomization energies of a group of 109 main-group molecules are considered at the same time, the MPW1B95/aug-cc-pVTZ single-level method (MUE = 2.7 kcal/mol) and the B2GP-PLYP and DSD-PLYP functionals with combinations of basis sets or using the doubly hybrid method (MUEs = 1.9-2.2 kcal/mol) give the overall best result. 相似文献
14.
《Acta Crystallographica. Section C, Structural Chemistry》2018,74(9):1026-1031
Two novel inclusion compounds of 4,4′‐sulfonyldibenzoate anions and tetrapropylammonium cations with different ancillary molecules of water and boric acid, namely bis(tetrapropylammonium) 4,4′‐sulfonyldibenzoate dihydrate, 2C12H28N+·C14H8O6S2−·H2O ( 1 ), and bis(tetrapropylammonium) 4,4′‐sulfonyldibenzoate bis(boric acid), 2C12H28N+·C14H8O6S2−·2H3BO3 ( 2 ), were prepared and characterized using single‐crystal X‐ray diffraction. In the two salts, the host 4,4′‐sulfonyldibenzoic acid molecules, which are converted to the corresponding anions under basic conditions, can be regarded as proton acceptors which link different proton donors of the ancillary molecules of water or boric acid. In this way, an isolated hydrogen‐bonded tetramer is constructed in salt 1 and a ribbon is constructed in salt 2 . The tetramers and ribbons are then packed in a repeating manner to generate various host frameworks, and the tetrapropylammonium guest counter‐ions are contained in the cavities of the host lattices to give the final stable crystal structures. In these two salts, although the host anion and guest cation are the same, the difference in the ancillary small molecules results in different structures, indicating the significance of ancillary molecules in the formation of crystal structures. 相似文献
15.
Yuta Yamamoto Shogo Nakano Fumio Seki Yasuteru Shigeta Sohei Ito Hiroaki Tokiwa Makoto Takeda 《Molecules (Basel, Switzerland)》2021,26(5)
Infection of hosts by morbilliviruses is facilitated by the interaction between viral hemagglutinin (H-protein) and the signaling lymphocytic activation molecule (SLAM). Recently, the functional importance of the n-terminal region of human SLAM as a measles virus receptor was demonstrated. However, the functional roles of this region in the infection process by other morbilliviruses and host range determination remain unknown, partly because this region is highly flexible, which has hampered accurate structure determination of this region by X-ray crystallography. In this study, we analyzed the interaction between the H-protein from canine distemper virus (CDV-H) and SLAMs by a computational chemistry approach. Molecular dynamics simulations and fragment molecular orbital analysis demonstrated that the unique His28 in the N-terminal region of SLAM from Macaca is a key determinant that enables the formation of a stable interaction with CDV-H, providing a basis for CDV infection in Macaca. The computational chemistry approach presented should enable the determination of molecular interactions involving regions of proteins that are difficult to predict from crystal structures because of their high flexibility. 相似文献
16.
ZHAO Jinjin LI Wei WANG Xuechen WEI Xiao ZHU Huiwen QU Wenshan MEN Dandan GAO Zhixiang WEI Bin GAO Hanfei WU Yuchen 《高等学校化学研究》2023,39(1):121-126
Organic memristors with low power consumption, fast write/erasure speed, and complementary metal-oxide-semiconductor(CMOS) compatibility have attracted tremendous attention to mimic biological synapses to realize neuromorphic computation in recent years. In this paper, organic resistive switching memory(ORSM) based on (Z)-3-(naphthalen-2-yl)-2-(4-nitrophenyl)acrylonitrile(NNA) and polymer poly(N-vinylcarbazole)(PVK) composite film was prepared by spin-coating method. Device performance based on NNA:PVK composite films with different mass fractions of NNA were systematically investigated. The ORSM based on PVK:40%(mass fraction) NNA composite film exhibited non-volatile and bipolar memory properties with a switching ratio(Ion/Ioff) of 24.1, endurance of 68 times and retention time of 104 s, a “SET” voltage(Vset) of -0.55 V and a “RESET” voltage(Vreset) of 2.35 V. The resistive switching was ascribed to the filling and vacant process of the charge traps induced by NNA and the inherent traps in PVK bulk. The holes trapping and de-trapping process occurred when the device was applied with a negative or positive bias, which caused the transforming of the conductive way of charges, that is the resistive behaviors in the macroscopic. This study provides a promising platform for the fabrication of ORSM with high performance. 相似文献
17.
基于制备接枝型分子印迹膜构建农药电位型电化学传感器及其检测性能研究 总被引:1,自引:0,他引:1
基于分子设计,以氯甲基化聚砜(CMPSF)为基膜,阴离子单体对苯乙烯磺酸钠(SSS)为功能单体,N,N'-亚甲基双丙烯酰胺(MBA)为交联剂,在表面引发体系-NH2/S2O2-8的作用下,采用"接枝聚合与分子印迹同步进行"的分子表面印迹新技术,制备了接枝型农药抗蚜威分子印迹膜(MIM)。采用红外光谱(FITR)和光学显微镜(OM)对该分子印迹膜进行表征,通过等温结合实验与竞争吸附实验,考察了抗蚜威分子印迹膜的分子识别性能与机理。以该印迹膜作为敏感膜,构建了抗蚜威电位型传感器,并对其检测性能进行了考察。结果表明,所制备的接枝型印迹膜对模板抗蚜威分子具有特异的识别选择性和优良的结合亲和性,结合容量高达92μg/cm2,相对于分子结构与抗蚜威相似的阿特拉津,印迹膜对抗蚜威的选择性系数为4.537。在p H 4.0的水介质中,传感器膜电极的电位响应与抗蚜威浓度对数在1.0×10-6~1.0×10-3mol/L范围内呈良好的线性关系(r=0.999 9),其检出限为2.5×10-8mol/L;以抗蚜威分子印迹膜为敏感膜所构建的电位型传感器,其构建过程简捷,检测灵敏准确,电位响应快速(t10 s)。 相似文献
18.
Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C6F5)3 下载免费PDF全文
Sebastian J. K. Forrest Jamie Clifton Dr. Natalie Fey Prof. Paul G. Pringle Dr. Hazel A. Sparkes Prof. Duncan F. Wass 《Angewandte Chemie (International ed. in English)》2015,54(7):2223-2227
A Lewis basic platinum(0)–CO complex supported by a diphosphine ligand and B(C6F5)3 act cooperatively, in a manner reminiscent of a frustrated Lewis pair, to activate small molecules such as hydrogen, CO2, and ethene. This cooperative Lewis pair facilitates the coupling of CO and ethene in a new way. 相似文献
19.
High‐Resolution Single‐Molecule Fluorescence Imaging of Zeolite Aggregates within Real‐Life Fluid Catalytic Cracking Particles 下载免费PDF全文
Zoran Ristanović Dr. Marleen M. Kerssens Alexey V. Kubarev Frank C. Hendriks Dr. Peter Dedecker Prof. Dr. Johan Hofkens Prof. Dr. Maarten B. J. Roeffaers Prof. Dr. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2015,54(6):1836-1840
Fluid catalytic cracking (FCC) is a major process in oil refineries to produce gasoline and base chemicals from crude oil fractions. The spatial distribution and acidity of zeolite aggregates embedded within the 50–150 μm‐sized FCC spheres heavily influence their catalytic performance. Single‐molecule fluorescence‐based imaging methods, namely nanometer accuracy by stochastic chemical reactions (NASCA) and super‐resolution optical fluctuation imaging (SOFI) were used to study the catalytic activity of sub‐micrometer zeolite ZSM‐5 domains within real‐life FCC catalyst particles. The formation of fluorescent product molecules taking place at Brønsted acid sites was monitored with single turnover sensitivity and high spatiotemporal resolution, providing detailed insight in dispersion and catalytic activity of zeolite ZSM‐5 aggregates. The results point towards substantial differences in turnover frequencies between the zeolite aggregates, revealing significant intraparticle heterogeneities in Brønsted reactivity. 相似文献
20.
研制了一种新型微电流放大器系统,用于检测琢-Hemolysin生物蛋白纳米通道在单分子检测实验中所产生的微弱电流信号(<100 pA)。在1 mol/L KCl、10 mmol/L Tris-HCl,1 mmol/L EDTA的缓冲液(pH 8.0)中测定了DNA-PEG-DNA交联物与纳米通道的穿越和碰撞信号。实验中使用3 kHz贝塞尔滤波器和100 kHz模数转换器来对电流进行采样。结果表明,此放大器系统能够有效降低电流记录过程中的噪音,有利于分辨待测物分子与纳米通道作用所产生的较小阻断的电流信号(<10 pA)。 相似文献